Bis(2,2′-bipyridine)(5-isothiocyanato-1,10-phenanthroline)ruthenium(II) bis(hexafluoridophosphate) acetonitrile solvate
نویسندگان
چکیده
The title compound, [Ru(C(10)H(8)N(2))(2)(C(13)H(7)N(3)S)](PF(6))(2)·CH(3)CN, was synthesized by the reaction of thio-phosgene and bis-(2,2'-bipyridine)(1,10-phenanthrolin-5-amine)ruthenium(II) bis-(hexa-fluoridophosphate). The Ru(II) atom adopts a slightly distorted octa-hedral RuN(6) coordinaton formed by four N atoms of two bipyridine ligands and by two N atoms of the 1,10-phenantroline ligand. The isothio-cyanate group is almost linear, with an N-C-S angle of 174.4 (6)°. Two of the three hexa-fluoridophosphate counter-anions are located on inversion centres.
منابع مشابه
Ruthenium-mediated selective cleavage of nitrogen–carbon bond of the diimine function. Synthesis, spectroscopic and redox properties of the complexes [Ru(L)2{OC6H4C(CH3) N H}][ClO4] (L=2,2 -bipyridine and 1,10-phenanthroline) and the crystal structure of the bipyridine derivative
The reactions of Ru(bpy)2(CO3) (bpy=2,2 -bipyridine) and Ru(phen)2(CO3) (phen=1,10-phenanthroline) with the binucleating phenolato diimine function, OH C6H4 C(CH3) N CH2 C6H4 CH2 N (CH3)C C6H4 OH, H2L in ethanol solvent under dinitrogen atmosphere result in ruthenium bipyridine/phenanthroline heterochelates [Ru(bpy)2/(phen)2L ](ClO4) 1 where L corresponds to the ketonic imine function O C6H4C(C...
متن کاملcis-Bis(2,2′-bipyridine-κ2 N,N′)bis(pyridin-4-amine-κN 1)ruthenium(II) bis(hexafluoridophosphate) acetonitrile monosolvate1
In the title complex, [Ru(C(10)H(8)N(2))(2)(C(5)H(6)N(2))(2)](PF(6))(2)·CH(3)CN, the Ru(II) atom is bonded to two α-diimine ligands, viz. 2,2'-bipyridine, in a cis configuration and to two 4-amino-pyridine (4Apy) ligands in the expected distorted octa-hedral configuration. The compound is isostructural with [Ru(C(10)H(8)N(2))(2)(C(5)H(6)N(2))(2)](ClO(4))(2)·CH(3)CN [Duan et al. (1999 ▶). J. Coo...
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متن کامل(4′-Ferrocenyl-2,2′:6′,2′′-terpyridine-κ3 N,N′,N′′)(1,10-phenanthroline-κ2 N,N′)copper(II) bis(perchlorate) acetonitrile solvate
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متن کاملcis-Bis(1,10-phenanthroline-κ2 N,N′)bis(pyridin-4-amine-κN 1)ruthenium(II) bis(hexafluoridophosphate)1
In the title complex, [Ru(C(12)H(8)N(2))(2)(C(5)H(6)N(2))(2)](PF(6))(2), the Ru(II) atom is bonded to two α-diimine ligands, viz. 1,10-phenanthroline (phen), in a cis configuration, in addition with with two 4-amino-pyridine (4Apy) ligands, resulting in a distorted octa-hedral coordination geometry. N-H⋯F hydrogen-bonding inter-actions play an important role in the crystal assembly: 2(1)-screw-...
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عنوان ژورنال:
دوره 65 شماره
صفحات -
تاریخ انتشار 2009